I'll start this off with this classic example. I believe it was David de Angelo who brought this one forward a few years ago.

It's from Gone with the Wind:

https://www.youtube.com/watch?v=nACj50uq6_s

Look how quickly he takes her from complaining to wanting to be kissed.

Another one here. Look at how he disarms the little princess.

http://www.youtube.com/watch?v=lrhNPS4nbmQ

And this one is Hank Moody. People around here don't like the character too much, because of his white knighting, but say what you want, this guy's got solid game. One big part of my game that I'm working on is "building a connection" with the woman, and Moody's got this down.

Anyway, the video comes with an analysis: http://www.youtube.com/watch?v=qJW4jIHTax8